Dynamics of quantum wave packets in complex molecules traced by 2D coherent electronic correlation spectroscopy
- Author(s)
- Tomas Mancal, Oliver Bixner, Niklas Christensson, Jürgen Hauer, Franz Milota, Alexandra Nemeth, Jaroslaw Sperling, Harald Kauffmann
- Abstract
Electronic and nuclear molecular wavepackets are a clear manifestation of the wavelike properties of matter at the very heart of quantum mechanics. In this work we demonstrate how electronic two-dimensional spectroscopy (2D) serves as a highly evolved tool for the simultaneous investigation of both phenomena. In further analysis and theoretical treatments, 2D spectra form an ideal basis for the discussion of electronic decoherence, vibrational relaxation and electron-phonon coupling.
- Organisation(s)
- Department of Organic Chemistry, Electronic Properties of Materials, Department of Physical Chemistry
- External organisation(s)
- Charles University Prague, Lund University, Ludwig-Maximilians-Universität München, Newport Spectra-Physics Gmbh
- Journal
- Procedia Chemistry
- Volume
- 3
- Pages
- 105-117
- No. of pages
- 13
- DOI
- https://doi.org/10.1016/j.proche.2011.08.017
- Publication date
- 2011
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 103015 Condensed matter, 104001 General chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/dynamics-of-quantum-wave-packets-in-complex-molecules-traced-by-2d-coherent-electronic-correlation-spectroscopy(0f87fa61-59a7-408d-a2c6-9bee6df85a76).html