Spectroelectrochemistry of intercalated single-walled carbon nanotubes

Author(s)
A. A. Eliseev, N. I. Verbitskiy, I. I. Verbitskiy, A. V. Lukashin, A. S. Kumskov, N. A. Kiselev
Abstract

The method of Raman spectroelectrochemical detection of charge transfer in doped single-walled carbon nanotubes is suggested and tested for the determination of the electronic structure of "1D crystal@SWNT" composites. Spectroelectrochemical study of CuCl@SWNT composites in resonant Raman conditions revealed a significant Kohn anomaly shift of ca. -0.7 eV corresponding to redox doping of metallic 1.4 nm nanotubes and related to Fermi level downshift. The obtained results are consistent with data available from XPS and optical spectroscopy.

Organisation(s)
Electronic Properties of Materials
External organisation(s)
Anuchin Research Institute and Museum of Anthropology, Universität zu Köln, Russian Academy of Sciences
Journal
Physica Status Solidi. B: Basic Research
Volume
253
Pages
1585-1589
No. of pages
5
ISSN
0370-1972
DOI
https://doi.org/10.1002/pssb.201600029
Publication date
08-2016
Peer reviewed
Yes
Austrian Fields of Science 2012
103015 Condensed matter
Keywords
ASJC Scopus subject areas
Electronic, Optical and Magnetic Materials, Condensed Matter Physics
Portal url
https://ucris.univie.ac.at/portal/en/publications/spectroelectrochemistry-of-intercalated-singlewalled-carbon-nanotubes(a800be6d-43ca-47db-9e2a-26242d83b8d1).html