Transport, magnetic and vibrational properties of chemically exfoliated few-layer graphene
- Author(s)
- Bence G. Markus, Ferenc Simon, Julio C. Chacon-Torres, Stephanie Reich, Peter Szirmai, Balint Nafradi, Laszlo Forro, Thomas Pichler, Philipp Vecera, Frank Hauke, Andreas Hirsch
- Abstract
We study the vibrational, magnetic and transport properties of Few Layer Graphene (FLG) using Raman and electron spin resonance spectroscopy and microwave conductivity measurements. FLG samples were produced using wet chemical exfoliation with different post-processing, namely ultrasound treatment, shear mixing, and magnetic stirring. Raman spectroscopy shows a low intensity D mode which attests a high sample quality. The G mode is present at 1580 cm(-1) as expected for graphene. The 2D mode consists of 2 components with varying intensities among the different samples. This is assigned to the presence of single and few layer graphene in the samples. Electron Spin Resonance (ESR) spectroscopy shows a main line in all types of materials with a width of about 1 mT and a g-factor in the range of 2.005-2.010. Paramagnetic defect centers with a uniaxial g-factor anisotropy are identified, which shows that these are related to the local sp2 bonds of the material. All kinds of investigated FLGs have a temperature dependent resistance which is compatible with a small gap semiconductor. The difference in resistance is related to the different grain size of the samples.
- Organisation(s)
- Electronic Properties of Materials
- External organisation(s)
- Budapest University of Technology and Economics, Freie Universität Berlin (FU), École polytechnique fédérale de Lausanne, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)
- Journal
- Physica Status Solidi. B: Basic Research
- Volume
- 252
- Pages
- 2438-2443
- No. of pages
- 6
- ISSN
- 0370-1972
- DOI
- https://doi.org/10.1002/pssb.201552296
- Publication date
- 11-2015
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 103015 Condensed matter
- Keywords
- ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials, Condensed Matter Physics
- Portal url
- https://ucris.univie.ac.at/portal/en/publications/transport-magnetic-and-vibrational-properties-of-chemically-exfoliated-fewlayer-graphene(f2c17d85-b60e-450c-ab1c-8ee40dbb2e91).html