Electron Spectroscopy of Single Quantum Objects To Directly Correlate the Local Structure to Their Electronic Transport and Optical Properties

Author(s)
Ryosuke Senga, Thomas Pichler, Kazu Suenaga
Abstract

Physical property of a single quantum object is governed by its precise atomic arrangement. The direct correlation of localized physical properties with the atomic structures has been therefore strongly desired but still limited in the theoretical studies. Here, we have successfully examined the localized electronic properties of individual carbon nanotubes by means of high-resolution electron energy-loss spectroscopy combined with high-resolution transmission electron microscopy. Well-separated sharp peaks at the carbon K(1s) absorption edge and in the valence-loss spectra are obtained from a single freestanding carbon nanotube with the local chiral index and unambiguously identified as the transitions between the van Hove singularities. The spectra features clearly vary upon the different areas even in the individual carbon nanotube. Variations in interband transitions, plasmonic behaviors, and unoccupied electronic structures are clearly attributed to the local irregular atomic arrangement such as topological defect and/or elastic bond stretching.

Organisation(s)
Electronic Properties of Materials
External organisation(s)
National Institute of Advanced Industrial Science and Technology (AIST)
Journal
Nano Letters: a journal dedicated to nanoscience and nanotechnology
Volume
16
Pages
3661-3667
No. of pages
7
ISSN
1530-6984
DOI
https://doi.org/10.1021/acs.nanolett.6b00825
Publication date
06-2016
Peer reviewed
Yes
Austrian Fields of Science 2012
Materials physics
Keywords
Portal url
https://ucris.univie.ac.at/portal/en/publications/electron-spectroscopy-of-single-quantum-objects-to-directly-correlate-the-local-structure-to-their-electronic-transport-and-optical-properties(3332d835-03ec-42cb-8fbb-35ef81e41c52).html