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Controlled Isotope Arrangement in C-13 Enriched Carbon Nanotubes

Authors/others:Koltai, J. (Eötvös Loránd University Budapest) Mezei, G. (Eötvös Loránd University Budapest) Zolyomi, V. (University of Manchester) Kurti, J. (Eötvös Loránd University Budapest) Kuzmany, H.Pichler, T.Simon, F. (Budapest University of Technology and Economics)
Abstract:We report the synthesis of a novel isotope engineered C-13-C-12 heteronuclear nanostructure: single-wall carbon nanotubes made of C-13 enriched clusters which are embedded in natural carbon regions. The material is synthesized with a high temperature annealing from C-13 enriched benzene and natural C-60, which are coencapsulated inside host SWCNTs in an alternating fashion. The Raman 2D line indicates that the C-13 isotopes are not distributed uniformly in the inner tubes. A semiempirical method based modeling of the Raman modes under C-13 isotope enrichment shows that experimental data is compatible with the presence of C-13 rich clusters which are embedded in a natural carbon containing matrix.
Language:English
Number of pages:5
Date of publication:29.12.2016
Journal title:The Journal of Physical Chemistry Part C (Nanomaterials and Interfaces)
Volume:120
Number:51
Pages:29520-29524
Links:
Digital Object Identifier (DOI):http://dx.doi.org/10.1021/acs.jpcc.6b11367
Publication Type:Article
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